MATERIAL SAFETY DATA SHEET
SECTION 1: IDENTIFICATION
Product name: Hand sanitizer
Other product identifiers: KAN-920E, KAN-920Q, KAN-920A, KAN-920B, Recommended use: Hand sanitizer. External use only.
This industrial SDS is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications please refer to the product label.
Manufacturer: EnviroWay Manufacturing Inc 2241 Hanselman Ave.
Saskatoon, SK S7L 6A7, Canada
Toll free: 1-888-274-0862, www.enviroway.ca Manufactured for: nikihk Manufacturing LLP Emergency phone:
Leak and Spill: 1-800-667-7525 (SASK SPILLS) for the Province of Saskatchewan
1-866-845-6037 (Environment Canada) for anywhere else Poison Control: 1-866-454-1212 (Saskatchewan)
SECTION 2: HAZARD IDENTIFICATION
Flammable liquids Category 2
Eye irritation Category 2
Skin corrosion /irritation Category 2
Specific Target Organ Toxicity – Single exposure Category 2
Signal word Danger
Highly flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation May cause damage to optic nerve.
Prevention Keep away from heat, hot surfaces, open flames, sparks. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical, lighting, ventilating equipment
|Use only non-sparking tools|
|Take precautionary measures against static discharge|
|Wear eye protection, face protection, protective clothing, protective gloves|
|Wash thoroughly after handling|
|Do not eat, drink or smoke when using this product|
|Do not breathe mist, spray, vapors|
|Response||IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam to extinguish IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. If eye irritation persists: Get medical advice/attention
IF exposed or concerned: Get medical advice/attention
|Storage||Store in a well-ventilated place. Keep cool|
|Store locked up|
|Disposal||Dispose of contents/container to comply with local, state and federal regulations|
SECTION 3: COMPOSITION
Pure substance/mixture: Mixture
The following ingredients have hazardous properties:
|Ingredient||CAS #||% by weight|
This product is a consumer product and therefore an SDS is not required. This SDS fully discloses any health and safety hazards but limits the disclosure of ingredient ranges for proprietary reasons.
SECTION 4: FIRST AID MEASURES
INHALATION: Remove the victim into the fresh air. Respiratory problems: consult a doctor/medical service IF ON SKIN: Rinse well with water. Take off contaminated clothing and wash beforereuse. If skin irritation occurs: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention.
INGESTION: Rinse mouth with water. Do not induce vomiting. Call the Poison Information Centre (1-866454-1212) SK, Canada Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: take him to the hospital immediately.
SECTION 5: FIRE FIGHTING MEASURES
Means of Extinction: Use DRY chemicals. Alcohol-resistant foam. BC powder. Carbon dioxide.
Unsuitable means of extinction: Water is generally unsuitable and may increase spreading the fire.
Special Fire Fighting Procedures: Use water spray to cool fire-exposed containers and structures. Use water spray to disperse vapours; re-ignition is possible. Vapours from this product and may travel or be moved by air currents, and ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from product handling point. Hazardous Decomposition/Combustion Materials: Carbon monoxide. Carbon dioxide and formaldehyde.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Leak and Spill Procedures: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large spill: Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with dry earth, sand or other Non-combustible material. Prevent entry into sewers, basements, or confined areas. Dike of needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the safety data sheet and with local authorities.
SECTION 7: HANDLING AND STORAGE
Precautions for safe handling
Do not ingest. Do not breathe gas/fumes/ vapor/ spray. Wear Personal Protective Equipment (PPE) Hand Protection: Nitrile or latex gloves have to be worn Eye Protection: Safety Goggles, full or halfface mask
Skin and Body Protection: Lab coat or coverall
Engineering Controls: Provide exhaust ventilation. Ensure that eyewash stations and safety showers are proximal to the workstation location. If ingested, seek medical advice immediately and show the container or label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis and moisture. Do not discharge the waste into the drain
7.2 Conditions for safe storage (including incompatible materials)
Keep locked up. Ground all equipment containing material. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above 23°C (73.4°F)
Others Good personal hygiene practices are suggested, such as abstaining from eating, drinking and smoking in the workplace
SECTION 8: PERSONAL PROTECTION
Exposure limits: Ethanol
TWA:1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000(ppm) from OSHA(PEL) [United States] TWA: 1900(mg/m3) from NIOSH [United States] TWA: 1000(ppm) from NIOSH TWA: 1000(ppm) from [United Kingdom (UK)] TWA:1920(mg/m3) from [United Kingdom (UK)] TWA:1000 STEL:1250(ppm) [Canada] Consult local authorities for acceptable exposer limits.
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. Acute toxicity of the vapor (LC50): 39000 mg/m3 4 hours [Mouse].
Provide exhaust ventilation or other engineering controls to keep airborne concentrations of vapours below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the workstation location.
Personal Protective Equipment (PPE)
Hand Protection: Nitrile or latex gloves have to be worn
Eye Protection: Safety Goggles, full or half-face mask Skin and Body Protection: Lab coat or coverall
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: liquid, colorless
Odour: typical alcohol odour
Odour Threshold (ppm): Information not available pH: not applicable
Melting Point/Freezing Point: Information not available
Initial Boiling Point/Range: Information not available
Flash point: 20°C
Evaporation Rate: Information not available
Flammability: Information not available
Upper/lower flammability/explosive limit: Information not available
Vapour Pressure (mmHg): Information not available
Vapour Density (air = 1): Information not available
Relative density: Information not available
Solubility in Water: Information not available
Partition coefficient: Information not available
Auto-ignition temperature: Information not available
Decomposition temperature: Information not available Viscosity: Information not available
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Material is stable under normal conditions Hazardous Polymerization: Not established.
Materials to Avoid: Strong oxidizing agents
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: TOXICOLOGICAL INFORMATION
Routes of exposure: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Inhalation: Prolonged inhalation may be harmful
Ingestion: Expected to be a low ingestion hazard.
Skin contact: Prolonged skin contact may cause temporary irritation Eye contact: Causes serious eye irritation
Symptoms related to the physical, chemical and toxicological characteristics
May cause gastrointestinal tract irritation with nausea, vomiting,
May affect behaviour/central nervous system (central nervous system depression – amnesia, headache, muscular incoordination, excitation, mild euphoria, slurred speech, drowsiness, staggering gait, fatigue, changes in mood/personality, excessive talking, dizziness, ataxia, somnolence, coma/ narcosis, hallucinations, distorted perceptions, general anesthetic), peripheral nervous system (spastic paralysis) vision (diplopia).
Delayed and immediate effects, and chronic effects from short-term and long-term exposure Carcinogenic Effects: Not classifiable for human or animal by ACGIH.
Mutagenic Effects: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.
Numerical measure of toxicity:
Oral: LD50 = 9288 mg/kg
Dermal: LD50 = 26,596 mg/kg
Inhalation: LC50 = 42,052 mg/L
SECTION 12: ECOLOGICAL INFORMATION
Toxicity: ingredient toxicity values with regards to the environment
|Ethanol||LC 50/96 Hour Oncorhynchus mykiss>10,000 mg/l||Not available||Pseudomonas Putida
SECTION 13: DISPOSAL CONSIDERATIONS
Spill: Contain spilled material. Provide adequate ventilation and protective equipment. Remove sources of heat, sparks or flames. Spill should be collected in suitable containers or absorbed on a suitable absorbent material for subsequent disposal.
Waste Disposal: Waste material should be disposed of in an approved incinerator or in a designated landfill site, in compliance with all federal, provincial, and local government regulations.
SECTION 14: TRANSPORT INFORMATION
UN number: 1987
UN proper shipping name Alcohols N.O.S. (ETHANOL)
Transport hazard class(es) Primary Class 3
Subsidiary Class NONE
Packing group (if applicable) II
Packing Group: II
EMS-No: F-E, S-D
Proper shipping name: ALCOHOLS, N.O.S. (ETHANOL) Marine pollutant: No
Class: 3 Packing
Proper shipping name: ALCOHOLS, N.O.S. (ETHANOL)
SECTION 15: REGULATORY INFORMATION
Canadian DSL Inventory Status: all ingredients are on the Domestic Substances List or exempt
SECTION 16: OTHER INFORMATION
Date of latest revision: Nov 29, 2020
Disclaimer – Notice to Reader
Nikihk Manufacturing LP, expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Do not use ingredient information and/or ingredient percentages in this MSDS as a product specification. All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, Nikihk makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Nikihk’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.